Determination of the recombination coefficient in electrolytic solutions from impedance spectroscopy measurements

نویسندگان

چکیده

The dependence of the actual/effective ionic concentration on nominal salt is experimentally investigated for aqueous solutions NaCl and KCl. actual bulk density determined by means impedance spectroscopy technique using two approaches data analysis: A first approach scrutinizing real part's plateau cell's electric spectrum versus dopant when written in series representation. second one via extraction from simultaneously fitting imaginary parts Poisson-Nernst-Planck model. validity this procedure reposes hypothesis that both diffusion coefficient dielectric constant are independent explored range concentrations. Our experimental results indicate a first-order reaction describes well dissociation phenomenon. dissociation-association ratio has been calculated. Deviations linearity appear at rather low concentrations order mM.

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ژورنال

عنوان ژورنال: Journal of Electroanalytical Chemistry

سال: 2022

ISSN: ['1873-2569', '1572-6657']

DOI: https://doi.org/10.1016/j.jelechem.2022.116070